Energy Services Bulletin, February 2004

Researchers, companies aim for efficient ultra-thin PV cells

Sliver technology uses innovative manufacturing techniques to produce individual cells of less than 70 microns thick—thinner than a human hair. The cells use 90 percent less silicon than current conventional solar PV modules. (photo courtesy of Origin Energy)

 

In spite of the benefits renewable energy has to offer, utilities often cite the cost of alternative technologies as a barrier to developing more distributed generation projects. Many renewable energy experts believe that the key to making renewable resources, such as solar power, more competitive with fossil fuels is to bring down the high cost of materials and production. Several companies are working on new techniques to make photovoltaic cells a more affordable—and versatile—option.

For conventional solar cells made of crystalline silicon, material cost is the most expensive part of the unit. Also, the silicon must be processed in elaborate clean-room facilities, like computer chips, adding to the production cost. The most promising solutions fall mainly into two categories: develop a manufacturing process that uses less crystalline silicon or make cells out of a different material.

Manufacturers believe thin is in for crystalline silicon solar cells
The Australian company Origin Energy is one of the leaders in the "less-material" camp with its patented Sliver Cell technology, developed in cooperation with Australian National University. According to Origin, the solar cells are less than 70 microns thick and convert 19.5 percent of the solar energy that hits them into electricity. Conventional industrial cells are about 300 micrometers thick and have an efficiency value of about 16 percent.

"Sliver Cell technology needs the equivalent of two silicon wafers to convert sunlight to 140 watts of power," explained Professor Andrew Blakers, director of the ANU Centre for Sustainable Energy Systems. "By comparison, a conventional solar panel needs about 60 silicon wafers to achieve this performance."

The manufacturers believe that the economy and flexibility of the paper-thin PV material will advance the adoption of solar power. Besides conventional uses, Sliver lends itself to such applications as flexible, roll-up solar panels, high-voltage solar-panels and solar powered aircraft, satellite and surveillance systems.

In late 2003, Origin started construction on a $20 million plant in Adelaide, Australia. The plant will produce up to 5 MW of PV modules per year initially, expandable to 25 MW per year to meet the potential export market. Sliver technology PV modules are expected to be available to market by January 2005.

Researchers at the Fraunhofer Institute for Solar Energy Systems in Germany are slicing their crystalline silicon even finer—nearly half the thickness of the Origin cells. The Fraunhofer ISE scientists claim to have produced a crystalline silicon solar cell that is only 37 microns thick and achieves a solar energy conversion efficiency of 20.2 percent.

The key to producing wafer-like cells is laser-fired contacts technology, an inexpensive process for attaching electrical connections to the cells. The process requires only one second per solar cell and works for all wafer thicknesses, making it ideal for industrial mass production. Stefan Glunz, the institute's coordinator for monocrystalline silicon solar cell research, said that considerable research is still needed to economically manufacture the extremely thin wafers.

Tokyo-based PV specialistsMSK achieve savings by making solar cells that are a little thinner—200 micrometers—rather than a lot thinner. The company's recently opened module production factory in Nagano, Japan, is geared to handle the thinner cells and keep pace with other advances in PV cell technology. The facility also has the economy of scale working for it with the capability to produce 45,000 solar modules per month. It is the world's largest module production capacity at a single site.

Academic research focuses on new PV materials
Flexible, "organic" PV material like malleable polymers offer a vastly less expensive and more versatile alternative to crystalline silicon, researchers say, although one that so far is considerably less efficient. Such PV "films" have existed since 1986, according to Princeton electrical engineering professor Stephen Forrest, but have efficiency rates of only 1 percent.

Forrest heads a team of university electrical engineers that invented a technique for producing a new class of ultra-thin, organic photovoltaics. As reported in the Sept. 11 issue of Nature, the researchers broke the one-percent efficiency barrier by changing the organic compounds used to make their solar cells, yielding devices with efficiencies of more than three percent.

The team's most recent advance involved finding a new method for forming the organic film, "which increased the efficiency by 50 percent," Forrest told the scientific journal. The innovation, he continued, could lead to cells being manufactured in a process something like printing or spraying the materials onto a roll of plastic, and then applying it to large surfaces.

The next phase of research will combine the new materials and techniques, with hopes of yielding at least five-percent efficiency. "We think we have pathway for using this and other tricks to get to 10-percent reasonably quickly," said Forrest.

On the other side of the country, researchers at the Berkeley campus of the University of California are working with nanocrystals of cadmium selenide, a light-sensitive semiconductor. Forbes magazine reported that chemistry graduate students at the university used the material to create a postage stamp-sized solar cell that generates 1.5 milliwatts, or 15 watts per square meter.

Ultra-thin PV films give new meaning to portable power source
The UC Berkeley chemistry department turned much of its research over to the nanotechnology firm Nanosys, Inc. in hopes that the company's resources will move development closer to commercialization. The company's goal is to embed nanocrystals of semiconductor material in cheap, bendable plastic sheets to create solar cells with 10 percent efficiency generating energy at $1 per watt.

Michigan-based Uni-Solar produces easy-to-handle sheets of solar material using vapor-deposited amorphous silicon alloy material. Because amorphous silicon absorbs light more efficiently, the cell's thickness can be up to 100 times thinner than a conventional cell, greatly reducing material costs. The material's advantages are in versatility, sturdiness and scalability. However, like other thin-film PV cells, the sheets don't approach the efficiency of some crystalline products.

The potential applications for flexible, efficient and affordable thin-film PV are so broad that the U.S. Army is partnering with industry to improve the technology. In August, the Army awarded a new round of funding to Konarka Technologies to develop a lightweight, portable power source to reduce the number of batteries soldiers must carry into combat.

The technology uses dye-coated titania nanocrystals applied to a flexible metallic foil or plastic base with the low-temperature sintering process that launched the company four years ago. The foil-based units boast efficiencies of about 7 percent while the less expensive plastic cells are about 5 percent efficient.

The color flexibility of the dye combined with Konarka's recent development of an actual PV fiber puts the possibility of a wearable power source within reach. In the future, troops may power sophisticated military electronic equipment in the field with solar panels woven into their uniforms. The same type of rollout recharging units will be available for civilian applications such as camping equipment. Konarka is targeting early 2005 for the commercialization of its first product.